Potentiometric Sensors with Ion-Exchange Donnan Exclusion Membranes

Potentiometric sensors with ion-exchange Donnan exclusion membranes.

Potentiometric sensors that exhibit a non-Hofmeister selectivity sequence are normally designed by selective chemical recognition elements in the membrane. In other situations, when used as detectors in separation science, for example, membranes that respond equally to most ions are preferred. With so-called liquid membranes, a low selectivity is difficult to accomplish since these membranes ar...

The Donnan Potentials of Polysulfonated Cation Exchange Membranes

Membrane potentials of polysulfonated cation exchange membranes (unsupported polysulfone, SA3S and polyester supported polysulfone, SA3T) for KCl, NaCl and LiCl solutions using Ag/AgCl electrodes were measured. The measurements were carried out for, KCl SA3S or SA3T MCL, (M: K, Na and Li) systems. The concentration of salt (KCl) was kept constant in one side of the cell, C1, at 1.10 M was chang...

Potentiometric pH response of polymer membranes incorporated with ion-exchangers.

Polymer membrane-based ion-, gas- and bio-selective potentiometric sensors.

Recent progress in the design of new polymer membrane-based potentiometric ion-, gas- and bio-selective electrodes in chemistry laboratories at the University of Michigan (Ann Arbor) is reviewed. Emphasis is placed on describing the performance of devices for measuring anions (e.g., salicylate, thiocyanate, chloride and heparin) and gases (e.g., ammonia, carbon dioxide and oxygen) in biological...

Electrodialysis of Blood Using Ion-Exchange Membranes

THE correction of electrolyte imbalance and the removal of retention products of the blood during renal failure is at present achieved by the use of artificial kidneys which permit the diffusion of solutes through a semi-permeable membrane. Several types of apparatus used successfully for hemodialysis include those described by Kolff and Watschinger (1956) and Alwall, Norviit, and Steins (1948)...